Communication: Visible line intensities of the triatomic hydrogen ion from experiment and theory.

نویسندگان

  • Annemieke Petrignani
  • Max H Berg
  • Florian Grussie
  • Andreas Wolf
  • Irina I Mizus
  • Oleg L Polyansky
  • Jonathan Tennyson
  • Nikolai F Zobov
  • Michele Pavanello
  • Ludwik Adamowicz
چکیده

The visible spectrum of H3(+) is studied using high-sensitivity action spectroscopy in a cryogenic radiofrequency multipole trap. Advances are made to measure the weak ro-vibrational transitions from the lowest rotational states of H3(+) up to high excitation energies providing visible line intensities and, after normalisation to an infrared calibration line, the corresponding Einstein B coefficients. Ab initio predictions for the Einstein B coefficients are obtained from a highly precise dipole moment surface of H3(+) and found to be in excellent agreement, even in the region where states have been classified as chaotic.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 141 24  شماره 

صفحات  -

تاریخ انتشار 2014